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NR 440.682(5)(d) (d) The administrator will treat applications under this subsection according to the following criteria, except in cases where he or she concludes that other criteria are appropriate:
NR 440.682(5)(d)1. 1. The applicant shall collect, verify and submit test data, covering a period of at least 12 months, necessary to support the finding in par. (a).
NR 440.682(5)(d)2. 2. If the applicant is an owner or operator of an affected facility, he or she shall commit in writing to operate and maintain the alternative means so as to achieve a reduction in VOC emissions at least equivalent to the reduction in VOC emissions achieved under the design, equipment, work practice or operational standard.
NR 440.682(6) (6)Recordkeeping requirements.
NR 440.682(6)(a)(a) Each owner or operator subject to the provisions of this section shall comply with the requirements of pars. (b) and (c) in addition to the requirements of s. NR 440.62 (7).
NR 440.682(6)(b) (b) The following recordkeeping requirements shall apply to pressure relief devices subject to the requirements of sub. (4) (b) 1.:
NR 440.682(6)(b)1. 1. When each leak is detected as specified in sub. (4) (b) 2., a weatherproof and readily visible identification, marked with the equipment identification number, shall be attached to the leaking equipment. The identification on the pressure relief device may be removed after it has been repaired.
NR 440.682(6)(b)2. 2. When each leak is detected as specified in sub. (4) (b) 2., the following information shall be recorded in a log and shall be kept for 2 years in a readily accessible location:
NR 440.682(6)(b)2.a. a. The instrument and operator identification numbers and the equipment identification number.
NR 440.682(6)(b)2.b. b. The date the leak was detected and the dates of each attempt to repair the leak.
NR 440.682(6)(b)2.c. c. Repair methods applied in each attempt to repair the leak.
NR 440.682(6)(b)2.d. d. “Above 10,000 ppm" if the maximum instrument reading measured by the methods specified in after each repair attempt is 10,000 ppm or greater.
NR 440.682(6)(b)2.e. e. “Repair delayed" and the reason for the delay if a leak is not repaired within 15 calendar days after discovery of the leak.
NR 440.682(6)(b)2.f. f. The signature of the owner or operator (or designate) whose decision it was that repair could not be effected without a process shutdown.
NR 440.682(6)(b)2.g. g. The expected date of successful repair of the leak if a leak is not repaired within 15 days.
NR 440.682(6)(b)2.h. h. Dates of process unit shutdowns that occur while the equipment is unrepaired.
NR 440.682(6)(b)2.i. i. The date of successful repair of the leak.
NR 440.682(6)(b)2.j. j. A list of identification numbers for equipment that are designated for no detectable emissions under the provisions of s. NR 440.62 (3) (d) 1. The designation of equipment subject to the provisions of s. NR 440.62 (3) (d) 1. signed by the owner or operator.
NR 440.682(6)(c) (c) An owner or operator shall comply with the following requirement in addition to the requirement of s. NR 440.62 (10): Information and data used to demonstrate that a reciprocating compressor is in wet gas service to apply for the exemption in sub. (4) (f) shall be recorded in a log that is kept in a readily accessible location.
NR 440.682(7) (7)Reporting requirements.
NR 440.682(7)(a)(a) Each owner or operator subject to the provisions of this section shall comply with the requirements of pars. (b) and (c) in addition to the requirements of s. NR 440.62 (8).
NR 440.682(7)(b) (b) An owner or operator shall include the following information in the initial semiannual report in addition to the information required in s. NR 440.62 (8) (b) 1. to 4.: number of pressure relief devices subject to the requirements of sub. (4) (b) except for those pressure relief devices designated for no detectable emission under the provision of s. NR 440.62 (3) (d) 1. and those pressure relief devices complying with s. NR 440.62 (3) (d) 3.
NR 440.682(7)(c) (c) An owner or operator shall include the following information in all semiannual reports in addition to the information required in s. NR 440.62 (8) (c) 2. a. to f.:
NR 440.682(7)(c)1. 1. Number of pressure relief devices for which leaks were detected as required in sub. (4) (b) 2. and
NR 440.682(7)(c)2. 2. Number of pressure relief devices for which leaks were not repaired as required in sub. (4) (b) 3.
NR 440.682 History History: Cr. Register, September, 1990, No. 417, eff. 10-1-90; am. (4) (b) 3. a., Register, July, 1993, No. 451, eff. 8-1-93; correction in (4) (b) and (d) made under s. 13.93 (2m) (b) 7., Register, November, 1999, No. 527; CR 06-109: am. (3) (f) and (4) (h) 1. and 2. Register May 2008 No. 629, eff. 6-1-08.
NR 440.684 NR 440.684Onshore natural gas processing: SO2 emissions.
NR 440.684(1)(1)Applicability and designation of affected facilities.
NR 440.684(1)(a)(a) The provisions of this section are applicable to the following affected facilities that process natural gas: each sweetening unit, and each sweetening unit followed by a sulfur recovery unit.
NR 440.684(1)(b) (b) Facilities that have a design capacity less than 2 long tons per day (LT/D) of hydrogen sulfide (H2S) in the acid gas (expressed as sulfur) are required to comply with sub. (8) (c) but are not required to comply with subs. (3) to (7).
NR 440.684(1)(c) (c) The provisions of this section are applicable to facilities located on land and include facilities located onshore which process natural gas produced from either onshore or offshore wells.
NR 440.684(1)(d) (d) The provisions of this section apply to each affected facility identified in par. (a) which commences construction or modification after January 20, 1984.
NR 440.684(1)(e) (e) The provisions of this section do not apply to sweetening facilities producing acid gas that is completely reinjected into oil-or-gas-bearing geologic strata or that is otherwise not released to the atmosphere.
NR 440.684(2) (2)Definitions and symbols.
NR 440.684(2)(a)(a) As used in this section, terms not defined in this subsection have the meanings given in s. NR 440.02.
NR 440.684(2)(a)1. 1. “Acid gas" means a gas stream of hydrogen sulfide (H2S) and carbon dioxide (CO2) that has been separated from sour natural gas by a sweetening unit.
NR 440.684(2)(a)2. 2. “Natural gas" means a naturally occurring mixture of a hydrocarbon and nonhydrocarbon gases found in geologic formations beneath the earth's surface. The principal hydrocarbon constituent is methane.
NR 440.684(2)(a)3. 3. “Onshore" means all facilities except those that are located in the territorial seas or on the outercontinental shelf.
NR 440.684(2)(a)4. 4. “Reduced sulfur compounds" means hydrogen sulfide (H2S), carbonyl sulfide (COS), and carbon disulfide (CS2).
NR 440.684(2)(a)5. 5. “Sulfur production rate" means the rate of liquid sulfur accumulation from the sulfur recovery unit.
NR 440.684(2)(a)6. 6. “Sulfur recovery unit" means a process device that recovers element sulfur from acid gas.
NR 440.684(2)(a)7. 7. “Sweetening unit" means a process device that separates the H2S and CO2 contents from the sour natural gas stream.
NR 440.684(2)(a)8. 8. “Total SO2 equivalents" means the sum of volumetric or mass concentrations of the sulfur compounds obtained by adding the quantity existing as SO2 to the quantity of SO2 that would be obtained if all reduced sulfur compounds were converted to SO2, ppmv or kg/dscm (lb/dscf).
NR 440.684(2)(b) (b) As used in this section, all symbols not defined in this subsection have the meanings given them in s. NR 440.03.
NR 440.684(2)(b)1. 1. “E" is the sulfur emission rate expressed as elemental sulfur in kg/hr (lb/hr), rounded to one decimal place.
NR 440.684(2)(b)2. 2. “R" is the sulfur emission reduction efficiency achieved in percent carried to one decimal place.
NR 440.684(2)(b)3. 3. “S" is the sulfur production rate in kg/hr (lb/hr), rounded to one decimal place.
NR 440.684(2)(b)4. 4. “X" is the sulfur feed rate from the sweetening unit, that is, the H2S in the acid gas, expressed as sulfur, Mg/d (long ton/day), rounded to one decimal place.
NR 440.684(2)(b)5. 5. “Y" is the sulfur content of the acid gas from the sweetening unit, expressed as mole percent H2S (dry basis) rounded to one decimal place.
NR 440.684(2)(b)6. 6. “Z" is the minimum required sulfur dioxide (SO2) emission reduction efficiency, expressed as percent carried to one decimal place. Zi refers to the reduction efficiency required at the initial performance test. Zc refers to the reduction efficiency required on a continual basis after compliance with Zi has been demonstrated.
NR 440.684(3) (3)Standards for sulfur dioxide.
NR 440.684(3)(a)(a) During the initial performance test required by s. NR 440.08 (2), each owner or operator shall achieve, at a minimum, an SO2 emission reduction efficiency (Zi) to be determined from Table 1 based on the sulfur feed rate (X) and the sulfur content of the acid gas (Y) of the affected facility.
NR 440.684(3)(b) (b) After demonstrating compliance with the provisions of par. (a), the owner or operator shall achieve, at a minimum, an SO2 emission reduction efficiency (Zc) to be determined from Table 2 based on the sulfur feed rate (X) and the sulfur content of the acid gas (Y) of the affected facility.
NR 440.684(4) (4)Compliance provisions.
NR 440.684(4)(a)1.1. To determine compliance with the standards for sulfur dioxide specified in sub. (3) (a), during the initial performance test as required by s. NR 440.08, the minimum required sulfur dioxide emissions reduction efficiency (Z) is compared to the emission reduction efficiency (R) achieved by the sulfur recovery technology.
NR 440.684(4)(a)1.a. a. If R is greater than or equal to Zi, the affected facility is in compliance.
NR 440.684(4)(a)1.b. b. If R is less than Zi, the affected facility is not in compliance.
NR 440.684(4)(a)2. 2. Following the initial determination of compliance as required by s. NR 440.08, any subsequent compliance determinations that may be required by the department shall compare R to Zc.
NR 440.684(4)(b) (b) The emission reduction efficiency (R) achieved by the sulfur recovery technology shall be determined using the procedures in sub. (5) (c) 1. - See PDF for table PDF - See PDF for table PDF
NR 440.684(5) (5)Test methods and procedures.
NR 440.684(5)(a)(a) In conducting the performance tests required in s. NR 440.08, the owner or operator shall use as reference methods and procedures the test methods in Appendix A of 40 CFR part 60, incorporated by reference in s. NR 440.17, or other methods and procedures as specified in this subsection, except as provided in s. NR 440.08 (2).
NR 440.684(5)(b) (b) During a performance test required by s. NR 440.08, the owner or operator shall determine the minimum required reduction efficiencies (Z) of SO2 emissions as required in sub. (3) (a) and (b) as follows:
NR 440.684(5)(b)1. 1. The average sulfur feed rate (X) shall be computed as follows: - See PDF for diagram PDF
where:
X is the average sulfur feed rate, Mg/d (long ton/day)
Qa is the average volumetric flow rate of acid gas from sweetening unit, dscm/day (dscf/day)
Y is the average H2S concentration in acid gas feed from sweetening unit, percent by volume, expressed as a decimal
K is (32kg S/kg-mole)/((24.04 dscm/kg-mole)(1000kg S/Mg)) = 1.331 x 10-3 Mg/dscm for metric units, and is (32 lb S/lb-mole)/((385.36 dscf/lb-mole)(2240 lb S/long ton)) = 3.707 x 10-5 long ton/dscf for English units
NR 440.684(5)(b)2. 2. The continuous readings from the process flowmeter shall be used to determine the average volumetric flow rate (Qa) in dscm/day (dscf/day) of the acid gas from the sweetening unit for each run.
NR 440.684(5)(b)3. 3. The Tutwiler procedure in sub. (9) or a chromatographic procedure following ASTM E260-96, incorporated by reference in s. NR 440.17 (2) (a) 75., shall be used to determine the H2S concentration in the acid gas feed from the sweetening unit. At least one sample per hour, at equally spaced intervals, shall be taken during each 4-hour run. The arithmetic mean of all samples shall be the average H2S concentration (Y) on a dry basis for the run. By multiplying the result from the Tutwiler procedure by 1.62 10-3, the units gr/100 scf are converted to volume percent.
NR 440.684(5)(b)4. 4. Using the information from par. (b) 1. and 3., Tables 1 and 2 shall be used to determine the required initial (Zi) and continuous (Zc) reduction efficiencies of SO2 emissions.
NR 440.684(5)(c) (c) The owner or operator shall determine compliance with the SO2 standards in sub. (3) (a) or (b) as follows:
NR 440.684(5)(c)1. 1. The emission reduction efficiency (R) achieved by the sulfur recovery technology shall be computed for each run using the following equation: - See PDF for diagram PDF
NR 440.684(5)(c)2. 2. The level indicators or manual soundings shall be used to measure the liquid sulfur accumulation rate in the product storage tanks. Readings taken at the beginning and end of each run, the tank geometry, sulfur density at the storage temperature and sample duration shall be used to determine the sulfur production rate (S) in kg/hr (lb/hr) for each run.
NR 440.684(5)(c)3. 3. The emission rate of sulfur shall be computed for each run as follows:
where:
E is the emission rate of sulfur per run, kg/hr (lb/hr)
Ce is the concentration of sulfur equivalent (SO 2 + reduced sulfur), g/dscm (lb/dscf)
Qsd is the volumetric flow rate of effluent gas, dscm/hr (dscf/hr)
K1 is a conversion factor, 1000 g/kg (7000 gr/lb)
NR 440.684(5)(c)4. 4. The concentration (Ce) of sulfur equivalent shall be the sum of the SO2 and TRS concentrations, after being converted to sulfur equivalents. For each run and each of the test methods specified in this paragraph, the sampling time shall be at least 4 hours. Method 1 shall be used to select the sampling site. The sampling point in the duct shall be at the centroid of the cross- section if the area is less than 5 m2 (54 ft 2) or at a point no closer to the walls than 1 m (39 in.) if the cross-sectional area is 5 m2 (54 ft2) or more and the centroid is more than 1 m (39 in.) from the wall.
NR 440.684(5)(c)4.a. a. Method 6 shall be used to determine the SO2 concentration. Eight samples of 20 minutes each shall be taken at 30-minute intervals. The arithmetic average shall be the concentration for the run. The concentration shall be multiplied by 0.5 10-3 to convert the results to sulfur equivalent.
NR 440.684(5)(c)4.b. b. Method 15 shall be used to determine the TRS concentration from reduction-type devices or where the oxygen content of the effluent gas is less than 1.0% by volume. The sampling rate shall be at least 3 liters/min (0.1 ft3/min) to insure minimum residence time in the sample line. Sixteen samples shall be taken at 15-minute intervals. The arithmetic average of all the samples shall be the concentration for the run. The concentration in ppm reduced sulfur as sulfur shall be multiplied by 1.333 10-3 to convert the results to sulfur equivalent.
NR 440.684(5)(c)4.c. c. Method 16A or 15 shall be used to determine the reduced sulfur concentration from oxidation-type devices or where the oxygen content of the effluent gas is greater than 1.0% by volume. Eight samples of 20 minutes each shall be taken at 30-minute intervals. The arithmetic average shall be the concentration for the run. The concentration in ppm reduced sulfur as sulfur shall be multiplied by 1.333 10-3 to convert the results to sulfur equivalent.
NR 440.684(5)(c)4.d. d. Method 2 shall be used to determine the volumetric flow rate of the effluent gas. A velocity traverse shall be conducted at the beginning and end of each run. The arithmetic average of the 2 measurements shall be used to calculate the volumetric flow rate (Qsd) for the run. For the determination of the effluent gas molecular weight, a single integrated sample over the 4-hour period may be taken and analyzed or grab samples at 1-hour intervals may be taken, analyzed and averaged. For the moisture content, 2 samples of at least 0.10 dscm (3.5 dscf) and 10 minutes shall be taken at the beginning of the 4-hour run and near the end of the time period. The arithmetic average of the 2 runs shall be the moisture content for the run.
NR 440.684(5)(d) (d) To comply with sub. (7) (d), the owner or operator shall obtain the information required by using the monitoring devices in par. (b) or (c).
NR 440.684(7) (7)Monitoring of emissions and operations.
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Published under s. 35.93, Stats. Updated on the first day of each month. Entire code is always current. The Register date on each page is the date the chapter was last published.